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Basic Oxides

                 Basic oxides or metallic oxides are formed when metals react with oxygen on hea  ng or without hea  ng.
                 Some metallic oxides are given in Table 6.2.

                                                 Table 6.2: Basic Oxides with their Formulae

                                                     Basic oxide            Formula
                                                Sodium oxide                  Na O
                                                                                 2
                                                Potassium oxide                K O
                                                                                2
                                                Ferrous(II) oxide              FeO
                                                Magnesium(II) oxide           MgO

                                                Calcium(II) oxide              CaO
                                                Copper(II) oxide              Cu O
                                                                                 2
                                                Zinc(II) oxide                 ZnO
                                                Lead oxide                     PbO


                     •  Most of the basic oxides o  en exist as solids at room temperature.
                     •  They are generally insoluble in water.
                     •  Some of these basic oxides dissolve in water to form soluble bases called alkalis.

                                 Na O(s)          +        H O(l)                    2NaOH(aq)
                                    2
                                                             2
                               Sodium oxide                 Water                 Sodium hydroxide
                                  K O(s)          +        H O(l)                     2KOH(aq)
                                   2
                                                             2
                              Potassium oxide               Water                Potassium hydroxide
                         Both sodium hydroxide and potassium hydroxide are strong alkalis. They turn red litmus paper
                        blue.
                 Note: All alkalis are bases but all bases are not alkalis.

                 Salts

                 Basic oxides react with acids to produce salts.

                               MgO(s)         +       2HCl(aq)                       MgCl (aq)       +     H O(l)
                                                                                                            2
                                                                                          2
                           Magnesium oxide      Dilute hydrochloric acid        Magnesium chloride         Water
                               CuO(s)         +      H SO (aq)                      CuSO (aq)        +     H O(l)
                                                          4
                                                       2
                                                                                                            2
                                                                                          4
                           Copper(II) oxide      Dilute sulphuric acid            Copper sulphate          Water
                 Neutral Oxides
                 The oxides which do not exhibit either acidic or basic proper  es are called  neutral oxides. Carbon
                 monoxide (CO) and nitrous oxide (NO) are neutral in natural and do not change the colour of indicators.
                 Amphoteric Oxides


                 Some metallic oxides like zinc oxide and aluminium oxide can react with both acids and bases to form salt
                 and water. They are called amphoteric oxides.


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