Page 124 - ICSE Chemistry 8
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3. Forma  on of precipitate: Some reac  ons are characterised by the forma  on of precipitate. A
                        precipitate is an insoluble solid formed during a chemical reac  on. It is indicated by a downwards
                        arrow ( ).
                                 
                        Examples:                                                                      Precipitate
                          •  When hydrogen sulphide gas is passed through blue-                A solid substance separated
                                                                                               from a solu  on is called a
                             coloured copper sulphate solu  on, a black precipitate of
                                                                                               precipitate.
                             copper sulphide is formed.
                                    CuSO (aq)       +     H S(g)               CuS(s)        +    H SO (aq)
                                                                                                        4
                                         4
                                                                                                    2
                                                           2
                                  Copper sulphate    Hydrogen sulphide        Copper sulphide    Sulphuric acid
                                       (blue)                                    (black ppt)
                          •  When ammonium hydroxide and iron sulphate solu  ons are mixed together, a dirty-green
                             precipitate of iron hydroxide is obtained.
                                  2NH OH(aq)        +   FeSO (aq)            Fe(OH) (s)      +    (NH ) SO (aq)
                                                                                     2
                                                             4
                                      4
                                                                                                       4 2
                                                                                                            4
                              Ammonium hydroxide    Iron sulphate             Iron hydroxide     Ammonium sulphate
                                                                         (dirty-green precipitate)
                          •  When sodium chloride and silver nitrate solu  ons are mixed together, a white precipitate of
                             silver chloride is formed.
                                   NaCl(aq)         + AgNO (aq)                AgCl(s)       +      NaNO (aq)
                                                             3
                                                                                                           3
                                 Sodium chloride      Silver nitrate          Silver chloride       Sodium nitrate
                                                                            (curdy white ppt)
                           Activity 6.3


                 Aim: To show the forma  on of a precipitate during a chemical reac  on
                 Materials required: Sodium sulphate solu  on, barium chloride solu  on, two test tubes
                 Procedure
                   •  Take a solu  on of sodium sulphate in a test tube and a solu  on of barium
                       chloride in another test tube.

                   •  Mix the two solu  ons.
                 Observa  on: Sodium sulphate and barium chloride react to form a white precipitate
                 of barium sulphate.                                                                               a white
                           Na SO (aq)    +      BaCl (aq)               BaSO (s)     +     2NaCl(aq)             precipitate
                                                                             4
                                                    2
                                 4
                             2
                         Sodium sulphate      Barium chloride         Barium sulphate     Sodium chloride
                                                                     (dense white ppt)
                 Conclusion: Mixing the solu  ons of sodium sulphate and barium sulphate leads to the forma  on of a
                 white precipitate.


                     4. Change of state: In many chemical reac  ons, a change of physical state is observed.

                        Examples:
                          •  Hydrogen and oxygen gases combine together to form water which is a liquid.
                                  2H (g)       +      O (g)                             2H O(l)
                                     2
                                                        2
                                                                                          2
                                 Hydrogen             Oxygen                            Water

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